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Though both parties have to download the app to begin chatting (unlike Face Time, which is baked into the dialer of compatible i Phones), it's still an intuitive app to use.Google's new video chat app has an interesting quirk: You can see a live video feed of who's calling you, even before you pick up the call.Think of it as a digital peephole, before you answer the door.This isn't Google's first foray into video calling.The company still has Hangouts, another video chat service, but that app is based on people's email addresses.